| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 19-10-13 15:00 | Real Madrid | FC Málaga | 2:0 |
| 19-10-13 17:00 | FC Valencia | Real Sociedad | 1:2 |
| 19-10-13 19:00 | CA Osasuna | FC Barcelona | 0:0 |
| 19-10-13 21:00 | Espanyol Barcelona | Atlético Madrid | 1:0 |
| 20-10-13 11:00 | FC Granada | FC Getafe | 0:2 |
| 20-10-13 16:00 | UD Almeria | Rayo Vallecano | 0:1 |
| 20-10-13 18:00 | Real Betis Sevilla | FC Elche | 1:2 |
| 20-10-13 20:00 | Real Valladolid | FC Sevilla | 2:2 |
| 21-10-13 19:00 | Celta Vigo | UD Levante | 0:1 |
| 21-10-13 21:00 | Athletic Bilbao | FC Villarreal | 2:0 |