| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 04-10-13 19:00 | FC Villarreal | FC Granada | 3:0 |
| 04-10-13 21:00 | FC Málaga | CA Osasuna | 0:1 |
| 05-10-13 15:00 | FC Elche | Espanyol Barcelona | 2:1 |
| 05-10-13 17:00 | Rayo Vallecano | Real Sociedad | 1:0 |
| 05-10-13 19:00 | UD Levante | Real Madrid | 2:3 |
| 05-10-13 21:00 | FC Barcelona | Real Valladolid | 4:1 |
| 06-10-13 11:00 | Atlético Madrid | Celta Vigo | 2:1 |
| 06-10-13 16:00 | FC Sevilla | UD Almeria | 2:1 |
| 06-10-13 18:00 | FC Getafe | Real Betis Sevilla | 3:1 |
| 06-10-13 20:00 | Athletic Bilbao | FC Valencia | 1:1 |