| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 27-09-13 20:00 | Real Valladolid | FC Málaga | 2:2 |
| 28-09-13 15:00 | FC Valencia | Rayo Vallecano | 1:0 |
| 28-09-13 17:00 | UD Almeria | FC Barcelona | 0:2 |
| 28-09-13 19:00 | Real Sociedad | FC Sevilla | 1:1 |
| 28-09-13 21:00 | Real Madrid | Atlético Madrid | 0:1 |
| 29-09-13 11:00 | CA Osasuna | UD Levante | 0:1 |
| 29-09-13 16:00 | Celta Vigo | FC Elche | 0:1 |
| 29-09-13 18:00 | Espanyol Barcelona | FC Getafe | 0:2 |
| 29-09-13 20:00 | Real Betis Sevilla | FC Villarreal | 1:0 |
| 30-09-13 21:00 | FC Granada | Athletic Bilbao | 2:0 |