| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 20-09-13 20:00 | CA Osasuna | FC Elche | 2:1 |
| 21-09-13 15:00 | Real Sociedad | FC Málaga | 0:0 |
| 21-09-13 17:00 | UD Almeria | UD Levante | 2:2 |
| 21-09-13 19:00 | Rayo Vallecano | FC Barcelona | 0:4 |
| 21-09-13 21:00 | Real Valladolid | Atlético Madrid | 0:2 |
| 22-09-13 11:00 | Real Betis Sevilla | FC Granada | 0:0 |
| 22-09-13 16:00 | Celta Vigo | FC Villarreal | 0:0 |
| 22-09-13 18:00 | Real Madrid | FC Getafe | 4:1 |
| 22-09-13 20:00 | FC Valencia | FC Sevilla | 3:1 |
| 23-09-13 21:00 | Espanyol Barcelona | Athletic Bilbao | 3:2 |