| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 14-09-13 15:00 | Atlético Madrid | UD Almeria | 4:2 |
| 14-09-13 17:00 | UD Levante | Real Sociedad | 0:0 |
| 14-09-13 19:00 | FC Barcelona | FC Sevilla | 3:2 |
| 14-09-13 21:00 | FC Villarreal | Real Madrid | 2:2 |
| 15-09-13 11:00 | FC Granada | Espanyol Barcelona | 0:1 |
| 15-09-13 16:00 | FC Getafe | CA Osasuna | 2:1 |
| 15-09-13 18:00 | FC Málaga | Rayo Vallecano | 5:0 |
| 15-09-13 20:00 | Real Betis Sevilla | FC Valencia | 3:1 |
| 16-09-13 19:00 | FC Elche | Real Valladolid | 0:0 |
| 16-09-13 21:00 | Athletic Bilbao | Celta Vigo | 3:2 |