| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 10-05-14 19:00 | FC Villarreal | Rayo Vallecano | 4:0 |
| 10-05-14 21:00 | UD Levante | FC Valencia | 2:0 |
| 11-05-14 16:00 | Athletic Bilbao | Real Sociedad | 1:1 |
| 11-05-14 18:00 | Real Betis Sevilla | Real Valladolid | 4:3 |
| 11-05-14 18:00 | Atlético Madrid | FC Málaga | 1:1 |
| 11-05-14 18:00 | Celta Vigo | Real Madrid | 2:0 |
| 11-05-14 18:00 | FC Granada | UD Almeria | 0:2 |
| 11-05-14 18:00 | Espanyol Barcelona | CA Osasuna | 1:1 |
| 11-05-14 18:00 | FC Getafe | FC Sevilla | 1:0 |
| 11-05-14 18:00 | FC Elche | FC Barcelona | 0:0 |