| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 25-04-14 20:00 | FC Elche | UD Levante | 1:1 |
| 26-04-14 15:00 | FC Granada | Rayo Vallecano | 0:3 |
| 26-04-14 17:00 | FC Getafe | FC Málaga | 1:0 |
| 26-04-14 19:00 | Real Madrid | CA Osasuna | 4:0 |
| 26-04-14 21:00 | Real Betis Sevilla | Real Sociedad | 0:1 |
| 27-04-14 11:00 | Espanyol Barcelona | UD Almeria | 1:2 |
| 27-04-14 16:00 | FC Valencia | Atlético Madrid | 0:1 |
| 27-04-14 18:00 | Athletic Bilbao | FC Sevilla | 3:1 |
| 27-04-14 20:00 | FC Villarreal | FC Barcelona | 2:3 |
| 28-04-14 21:00 | Celta Vigo | Real Valladolid | 4:1 |