| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 18-04-14 19:30 | Atlético Madrid | FC Elche | 2:0 |
| 19-04-14 15:00 | CA Osasuna | FC Valencia | 1:1 |
| 19-04-14 17:00 | UD Levante | FC Getafe | 0:0 |
| 19-04-14 19:00 | Real Sociedad | Espanyol Barcelona | 2:1 |
| 20-04-14 11:00 | UD Almeria | Celta Vigo | 2:4 |
| 20-04-14 16:00 | Rayo Vallecano | Real Betis Sevilla | 3:1 |
| 20-04-14 18:00 | FC Sevilla | FC Granada | 4:0 |
| 20-04-14 20:00 | FC Barcelona | Athletic Bilbao | 2:1 |
| 21-04-14 21:00 | FC Málaga | FC Villarreal | 2:0 |
| 07-05-14 20:00 | Real Valladolid | Real Madrid | 1:1 |