| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 11-04-14 20:00 | CA Osasuna | Real Valladolid | 0:0 |
| 12-04-14 15:00 | Celta Vigo | Real Sociedad | 2:2 |
| 12-04-14 17:00 | FC Villarreal | UD Levante | 1:0 |
| 12-04-14 19:00 | FC Granada | FC Barcelona | 1:0 |
| 12-04-14 21:00 | Real Madrid | UD Almeria | 4:0 |
| 13-04-14 11:00 | Real Betis Sevilla | FC Sevilla | 0:2 |
| 13-04-14 16:00 | FC Valencia | FC Elche | 2:1 |
| 13-04-14 18:00 | FC Getafe | Atlético Madrid | 0:2 |
| 13-04-14 20:00 | Espanyol Barcelona | Rayo Vallecano | 2:2 |
| 14-04-14 21:00 | Athletic Bilbao | FC Málaga | 3:0 |