| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 04-04-14 20:00 | UD Almeria | CA Osasuna | 1:2 |
| 05-04-14 15:00 | Atlético Madrid | FC Villarreal | 1:0 |
| 05-04-14 17:00 | FC Barcelona | Real Betis Sevilla | 3:1 |
| 05-04-14 19:00 | Real Sociedad | Real Madrid | 0:4 |
| 05-04-14 21:00 | Rayo Vallecano | Celta Vigo | 3:0 |
| 06-04-14 11:00 | FC Málaga | FC Granada | 4:1 |
| 06-04-14 16:00 | FC Elche | FC Getafe | 1:0 |
| 06-04-14 18:00 | FC Sevilla | Espanyol Barcelona | 4:1 |
| 06-04-14 20:00 | Real Valladolid | FC Valencia | 0:0 |
| 07-04-14 21:00 | UD Levante | Athletic Bilbao | 1:2 |