| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 30-08-13 22:00 | Rayo Vallecano | UD Levante | 1:2 |
| 30-08-13 22:00 | UD Almeria | FC Elche | 2:2 |
| 31-08-13 18:00 | Celta Vigo | FC Granada | 1:1 |
| 31-08-13 20:00 | Real Valladolid | FC Getafe | 1:0 |
| 31-08-13 22:00 | CA Osasuna | FC Villarreal | 0:3 |
| 01-09-13 11:00 | Real Madrid | Athletic Bilbao | 3:1 |
| 01-09-13 16:00 | Espanyol Barcelona | Real Betis Sevilla | 0:0 |
| 01-09-13 18:00 | Real Sociedad | Atlético Madrid | 1:2 |
| 01-09-13 20:00 | FC Sevilla | FC Málaga | 2:2 |
| 01-09-13 20:00 | FC Valencia | FC Barcelona | 2:3 |