| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 08-03-14 15:00 | Real Valladolid | FC Barcelona | 1:0 |
| 08-03-14 17:00 | Real Betis Sevilla | FC Getafe | 2:0 |
| 08-03-14 19:00 | Celta Vigo | Atlético Madrid | 0:2 |
| 08-03-14 21:00 | FC Granada | FC Villarreal | 2:0 |
| 09-03-14 11:00 | Espanyol Barcelona | FC Elche | 3:1 |
| 09-03-14 16:00 | UD Almeria | FC Sevilla | 1:3 |
| 09-03-14 18:00 | Real Madrid | UD Levante | 3:0 |
| 09-03-14 20:00 | FC Valencia | Athletic Bilbao | 1:1 |
| 10-03-14 19:00 | CA Osasuna | FC Málaga | 0:2 |
| 10-03-14 21:00 | Real Sociedad | Rayo Vallecano | 2:3 |