| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 21-02-14 20:00 | Real Valladolid | UD Levante | 1:1 |
| 22-02-14 15:00 | Real Madrid | FC Elche | 3:0 |
| 22-02-14 17:00 | Celta Vigo | FC Getafe | 1:1 |
| 22-02-14 19:00 | Real Sociedad | FC Barcelona | 3:1 |
| 22-02-14 21:00 | UD Almeria | FC Málaga | 0:0 |
| 23-02-14 11:00 | Rayo Vallecano | FC Sevilla | 0:1 |
| 23-02-14 16:00 | Real Betis Sevilla | Athletic Bilbao | 0:2 |
| 23-02-14 18:00 | FC Valencia | FC Granada | 2:1 |
| 23-02-14 20:00 | CA Osasuna | Atlético Madrid | 3:0 |
| 24-02-14 21:00 | Espanyol Barcelona | FC Villarreal | 1:2 |