| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 14-02-14 20:00 | FC Elche | CA Osasuna | 0:0 |
| 15-02-14 15:00 | Atlético Madrid | Real Valladolid | 3:0 |
| 15-02-14 17:00 | UD Levante | UD Almeria | 1:0 |
| 15-02-14 19:00 | FC Barcelona | Rayo Vallecano | 6:0 |
| 15-02-14 21:00 | FC Villarreal | Celta Vigo | 0:2 |
| 16-02-14 11:00 | FC Granada | Real Betis Sevilla | 1:0 |
| 16-02-14 16:00 | FC Getafe | Real Madrid | 0:3 |
| 16-02-14 18:00 | Athletic Bilbao | Espanyol Barcelona | 1:2 |
| 16-02-14 20:00 | FC Sevilla | FC Valencia | 0:0 |
| 17-02-14 21:00 | FC Málaga | Real Sociedad | 0:1 |