| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 07-02-14 20:00 | Espanyol Barcelona | FC Granada | 1:0 |
| 08-02-14 15:00 | FC Valencia | Real Betis Sevilla | 5:0 |
| 08-02-14 17:00 | Rayo Vallecano | FC Málaga | 4:1 |
| 08-02-14 19:00 | Real Madrid | FC Villarreal | 4:2 |
| 08-02-14 21:00 | UD Almeria | Atlético Madrid | 2:0 |
| 09-02-14 11:00 | CA Osasuna | FC Getafe | 2:0 |
| 09-02-14 16:00 | Real Valladolid | FC Elche | 2:2 |
| 09-02-14 18:00 | Real Sociedad | UD Levante | 0:0 |
| 09-02-14 20:00 | FC Sevilla | FC Barcelona | 1:4 |
| 10-02-14 21:00 | Celta Vigo | Athletic Bilbao | 0:0 |