| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 31-01-14 20:00 | FC Granada | Celta Vigo | 1:2 |
| 01-02-14 15:00 | FC Barcelona | FC Valencia | 2:3 |
| 01-02-14 17:00 | UD Levante | Rayo Vallecano | 0:0 |
| 01-02-14 19:00 | FC Getafe | Real Valladolid | 0:0 |
| 01-02-14 21:00 | FC Málaga | FC Sevilla | 3:2 |
| 02-02-14 11:00 | FC Elche | UD Almeria | 1:0 |
| 02-02-14 16:00 | Real Betis Sevilla | Espanyol Barcelona | 2:0 |
| 02-02-14 18:00 | Atlético Madrid | Real Sociedad | 4:0 |
| 02-02-14 20:00 | Athletic Bilbao | Real Madrid | 1:1 |
| 03-02-14 21:00 | FC Villarreal | CA Osasuna | 3:1 |