| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 23-08-13 19:00 | FC Getafe | UD Almeria | 2:2 |
| 23-08-13 21:00 | Athletic Bilbao | CA Osasuna | 2:0 |
| 24-08-13 18:00 | FC Elche | Real Sociedad | 1:1 |
| 24-08-13 20:00 | Espanyol Barcelona | FC Valencia | 3:1 |
| 24-08-13 22:00 | FC Villarreal | Real Valladolid | 2:1 |
| 25-08-13 18:00 | Atlético Madrid | Rayo Vallecano | 5:0 |
| 25-08-13 20:00 | FC Málaga | FC Barcelona | 0:1 |
| 25-08-13 20:00 | UD Levante | FC Sevilla | 0:0 |
| 25-08-13 22:00 | Real Betis Sevilla | Celta Vigo | 1:2 |
| 26-08-13 20:00 | FC Granada | Real Madrid | 0:1 |