| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 10-01-14 20:00 | FC Granada | Real Valladolid | 4:0 |
| 11-01-14 15:00 | Athletic Bilbao | UD Almeria | 6:1 |
| 11-01-14 17:00 | Celta Vigo | FC Valencia | 2:1 |
| 11-01-14 19:00 | Atlético Madrid | FC Barcelona | 0:0 |
| 11-01-14 21:00 | FC Elche | FC Sevilla | 1:1 |
| 12-01-14 11:00 | FC Getafe | Rayo Vallecano | 0:1 |
| 12-01-14 16:00 | Real Betis Sevilla | CA Osasuna | 1:2 |
| 12-01-14 18:00 | Espanyol Barcelona | Real Madrid | 0:1 |
| 12-01-14 20:00 | UD Levante | FC Málaga | 1:0 |
| 13-01-14 21:00 | FC Villarreal | Real Sociedad | 5:1 |