| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 04-01-14 15:00 | FC Málaga | Atlético Madrid | 0:1 |
| 04-01-14 17:00 | Real Valladolid | Real Betis Sevilla | 0:0 |
| 04-01-14 19:00 | FC Valencia | UD Levante | 2:0 |
| 04-01-14 21:00 | UD Almeria | FC Granada | 3:0 |
| 05-01-14 11:00 | FC Sevilla | FC Getafe | 3:0 |
| 05-01-14 15:00 | FC Barcelona | FC Elche | 4:0 |
| 05-01-14 17:00 | CA Osasuna | Espanyol Barcelona | 1:0 |
| 05-01-14 19:00 | Real Sociedad | Athletic Bilbao | 2:0 |
| 06-01-14 18:00 | Real Madrid | Celta Vigo | 3:0 |
| 06-01-14 21:00 | Rayo Vallecano | FC Villarreal | 2:5 |