| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 29-11-13 19:00 | FC Getafe | UD Levante | 1:0 |
| 29-11-13 19:30 | FC Villarreal | FC Málaga | 1:1 |
| 30-11-13 15:00 | FC Elche | Atlético Madrid | 0:2 |
| 30-11-13 17:00 | Celta Vigo | UD Almeria | 3:1 |
| 30-11-13 19:00 | Real Madrid | Real Valladolid | 4:0 |
| 30-11-13 21:00 | Espanyol Barcelona | Real Sociedad | 1:2 |
| 01-12-13 11:00 | Real Betis Sevilla | Rayo Vallecano | 2:2 |
| 01-12-13 16:00 | FC Granada | FC Sevilla | 1:2 |
| 01-12-13 18:00 | FC Valencia | CA Osasuna | 3:0 |
| 01-12-13 20:00 | Athletic Bilbao | FC Barcelona | 1:0 |