| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 22-11-13 20:00 | Real Valladolid | CA Osasuna | 0:1 |
| 23-11-13 15:00 | FC Barcelona | FC Granada | 4:0 |
| 23-11-13 17:00 | Real Sociedad | Celta Vigo | 4:3 |
| 23-11-13 19:00 | UD Almeria | Real Madrid | 0:5 |
| 23-11-13 21:00 | Atlético Madrid | FC Getafe | 7:0 |
| 24-11-13 11:00 | UD Levante | FC Villarreal | 0:3 |
| 24-11-13 16:00 | Rayo Vallecano | Espanyol Barcelona | 1:4 |
| 24-11-13 18:00 | FC Elche | FC Valencia | 2:1 |
| 24-11-13 20:00 | FC Sevilla | Real Betis Sevilla | 4:0 |
| 25-11-13 21:00 | FC Málaga | Athletic Bilbao | 1:2 |