| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 08-11-13 19:00 | CA Osasuna | UD Almeria | 0:1 |
| 08-11-13 21:00 | FC Granada | FC Málaga | 3:1 |
| 09-11-13 15:00 | Real Madrid | Real Sociedad | 5:1 |
| 09-11-13 17:00 | FC Getafe | FC Elche | 1:1 |
| 09-11-13 19:00 | Athletic Bilbao | UD Levante | 2:1 |
| 09-11-13 21:00 | Celta Vigo | Rayo Vallecano | 0:2 |
| 10-11-13 11:00 | Espanyol Barcelona | FC Sevilla | 1:3 |
| 10-11-13 16:00 | FC Valencia | Real Valladolid | 2:2 |
| 10-11-13 18:00 | FC Villarreal | Atlético Madrid | 1:1 |
| 10-11-13 20:00 | Real Betis Sevilla | FC Barcelona | 1:4 |