| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 01-11-13 20:00 | FC Barcelona | Espanyol Barcelona | 1:0 |
| 02-11-13 15:00 | Real Sociedad | CA Osasuna | 5:0 |
| 02-11-13 17:00 | UD Almeria | Real Valladolid | 1:0 |
| 02-11-13 19:00 | Rayo Vallecano | Real Madrid | 2:3 |
| 02-11-13 21:00 | FC Sevilla | Celta Vigo | 0:1 |
| 03-11-13 11:00 | FC Getafe | FC Valencia | 0:1 |
| 03-11-13 16:00 | Atlético Madrid | Athletic Bilbao | 2:0 |
| 03-11-13 18:00 | UD Levante | FC Granada | 0:1 |
| 03-11-13 20:00 | FC Málaga | Real Betis Sevilla | 3:2 |
| 04-11-13 21:00 | FC Elche | FC Villarreal | 0:1 |