| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 29-10-13 19:00 | Espanyol Barcelona | FC Málaga | 0:0 |
| 29-10-13 21:00 | Celta Vigo | FC Barcelona | 0:3 |
| 30-10-13 19:00 | FC Valencia | UD Almeria | 1:2 |
| 30-10-13 19:00 | Real Valladolid | Real Sociedad | 2:2 |
| 30-10-13 21:00 | Real Madrid | FC Sevilla | 7:3 |
| 30-10-13 21:00 | CA Osasuna | Rayo Vallecano | 3:1 |
| 31-10-13 19:00 | FC Villarreal | FC Getafe | 0:2 |
| 31-10-13 19:00 | FC Granada | Atlético Madrid | 1:2 |
| 31-10-13 21:00 | Athletic Bilbao | FC Elche | 2:2 |
| 31-10-13 21:00 | Real Betis Sevilla | UD Levante | 0:0 |