| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 25-10-13 20:00 | Rayo Vallecano | Real Valladolid | 0:3 |
| 26-10-13 15:00 | FC Málaga | Celta Vigo | 0:5 |
| 26-10-13 17:00 | FC Barcelona | Real Madrid | 2:1 |
| 26-10-13 19:00 | FC Elche | FC Granada | 0:1 |
| 26-10-13 21:00 | UD Levante | Espanyol Barcelona | 3:0 |
| 27-10-13 11:00 | FC Sevilla | CA Osasuna | 2:1 |
| 27-10-13 16:00 | FC Villarreal | FC Valencia | 4:1 |
| 27-10-13 18:00 | Real Sociedad | UD Almeria | 3:0 |
| 27-10-13 20:00 | Atlético Madrid | Real Betis Sevilla | 5:0 |
| 28-10-13 21:00 | FC Getafe | Athletic Bilbao | 0:1 |