| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 17-08-13 18:00 | Real Sociedad | FC Getafe | 2:0 |
| 17-08-13 20:00 | Real Valladolid | Athletic Bilbao | 1:2 |
| 17-08-13 22:00 | FC Valencia | FC Málaga | 1:0 |
| 18-08-13 18:00 | FC Barcelona | UD Levante | 7:0 |
| 18-08-13 20:00 | Real Madrid | Real Betis Sevilla | 2:1 |
| 18-08-13 20:00 | CA Osasuna | FC Granada | 1:2 |
| 18-08-13 22:00 | FC Sevilla | Atlético Madrid | 1:3 |
| 19-08-13 19:00 | Rayo Vallecano | FC Elche | 3:0 |
| 19-08-13 21:00 | UD Almeria | FC Villarreal | 2:3 |
| 19-08-13 21:00 | Celta Vigo | Espanyol Barcelona | 2:2 |