| Data | Casa | Visitante | Resultado |
|---|---|---|---|
| 05-10-18 20:00 | Athletic Bilbao | Real Sociedad | 1:3 |
| 06-10-18 12:00 | FC Girona | SD Eibar | 2:3 |
| 06-10-18 15:15 | FC Getafe | UD Levante | 0:1 |
| 06-10-18 17:30 | Deportivo Alavés | Real Madrid | 1:0 |
| 06-10-18 19:45 | CD Leganés | Rayo Vallecano | 1:0 |
| 07-10-18 11:00 | Real Valladolid | SD Huesca | 1:0 |
| 07-10-18 15:15 | Atlético Madrid | Real Betis Sevilla | 1:0 |
| 07-10-18 17:30 | Espanyol Barcelona | FC Villarreal | 3:1 |
| 07-10-18 17:30 | FC Sevilla | Celta Vigo | 2:1 |
| 07-10-18 19:45 | FC Valencia | FC Barcelona | 1:1 |