Calendário
| Data | Prazo para submeter os prognósticos | Casa | Visitante | Resultado | Regra de pontuação |
|---|---|---|---|---|---|
| 23-02-23 17:45 | 23-02-23 17:45 | AS Mónaco | Bayer 04 Leverkusen | 5:8a.pen. | 2 - 4 pontos |
| 23-02-23 17:45 | 23-02-23 17:45 | PSV Eindhoven | FC Sevilla | 2:0 | 2 - 4 pontos |
| 23-02-23 17:45 | 23-02-23 17:45 | FC Nantes | Juventus Turim | 0:3 | 2 - 4 pontos |
| 23-02-23 17:45 | 23-02-23 17:45 | FC Midtjylland | Sporting | 0:4 | 2 - 4 pontos |
| 23-02-23 20:00 | 23-02-23 20:00 | 1. FC Union Berlim | Ajax Amsterdão | 3:1 | 2 - 4 pontos |
| 23-02-23 20:00 | 23-02-23 20:00 | AS Roma | FC Red Bull Salzburgo | 2:0 | 2 - 4 pontos |
| 23-02-23 20:00 | 23-02-23 20:00 | Manchester United | FC Barcelona | 2:1 | 2 - 4 pontos |
| 23-02-23 20:00 | 23-02-23 20:00 | Stade Rennes | Shaktiar Donetsk | 6:6a.pen. | 2 - 4 pontos |